پیوندهای مفید
اخبار و اعلانات
آمار
| تعداد نشریات | 25 |
| تعداد شماره‌ها | 916 |
| تعداد مقالات | 7,521 |
| تعداد مشاهده مقاله | 12,227,507 |
| تعداد دریافت فایل اصل مقاله | 8,648,429 |
مقاله پژوهشی: تأثیر شرایط و روش لایه‌نشانی در خواص فیزیکی لایههای MAPbI3 به منظور استفاده در سلول خورشیدی پروسکایتی | ||
| فیزیک کاربردی ایران | ||
| دوره 10، شماره 4 - شماره پیاپی 23، دی 1399، صفحه 55-66 اصل مقاله (3.28 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22051/ijap.2021.34610.1191 | ||
| نویسندگان | ||
| نفیسه معماریان* 1؛ رضا رجب بلوکات2 | ||
| 1استادیار، دانشکدۀ فیزیک، دانشگاه سمنان، سمنان، ایران | ||
| 2دانش آموختۀ کارشناسی ارشد، دانشکدۀ فیزیک، دانشگاه سمنان، سمنان، ایران | ||
| چکیده | ||
| در سالهای اخیر سلول‌های خورشیدی با جاذب پروسکایت به دلیل افزایش فوقالعادۀ بازده، شدیداً مورد توجه محققان قرار گرفتهاند. در این پژوهش لایههای نازک پروسکایت متیل آمونیم سرب یدید (MAPbI3) به روش رشد دومرحلهای تهیه شده است. دو روش چرخشی‌ـ‌چرخشی و چرخشی‌ـ‌غوطهوری شد و ویژگیهای فیزیکی لایههای به‌دست‌آمده از این روشها مقایسه شد. ویژگیهای اپتیکی و ساختاری آن‌ها توسط روش‌های UV-VIS ، XRD و FE-SEM بررسی شده است. نتایج حاصل از بررسیهای ساختاری، فاز مکعبی را برای پروسکایت MAPbI3 نشان داد. همچنین مورفولوژی سطح لایه‌ها در تصاویر FE-SEM مشخص شد، که تشکیل یک لایۀ منسجم، بدون هیچگونه ترک و ناپیوستگی را تأیید میکند. نتایج نشان داد که گاف اپتیکی نمونه‌ها در بازۀ eV 59/1- 54/1 است. همچنین اثر تغییر غلظت مادۀ اولیه بر خواص فیزیکی لایههای MAPbI3 تهیه‌شده به هر دو روش، مشخص شد. نتایج نشان داد که در هر دو روش با افزایش غلظت PbI2 لایههای با ضخامت و جذب بیشتر ساخته میشود. | ||
| کلیدواژه‌ها | ||
| جاذب پروسکایت؛ متیل آمونیم سرب یدید؛ لایۀ نازک؛ لایه‌نشانی چرخشی؛ لایه‌نشانی غوطه‌وری | ||
| عنوان مقاله [English] | ||
| Research Paper: Effect of Deposition Condition and Method on Physical Properties of MAPbI3 Layers for Perovskite Solar Cell Purpose | ||
| نویسندگان [English] | ||
| Nafiseh Memarian1؛ Reza Rajab Bolookat2 | ||
| 1Assistant Professor, Faculty of Physics, Semnan University, Semnan, Iran | ||
| 2M.Sc. in Physics, Faculty of Physics, Semnan University, Semnan, Iran. | ||
| چکیده [English] | ||
| In recent years, solar cells with perovskite absorber have attracted considerable attention due to rapid increase in their efficiency. In this research, MAPbI3 layers were coated by a two-step method. Spin-spin and spin-dip methods were studied and physical properties of prepared layers were compared. Their optical and structural properties were investigated by UV-VIS, XRD and FE-SEM techniques. The results of structural analysis showed the formation of cubic phase for MAPbI3 perovskite. In addition, the surface morphology of the layers was determined by FE-SEM images, which confirmed the formation of a uniform and cohesive layer, without any cracks or discontinuities on the surface of layer. Results showed that the optical band gap of the samples are in the range of 1.54-1.59 eV. Furthermore, the effect of precursor concentration on the physical properties of MAPbI3 layers prepared by both methods (spin-spin and spin-dip) was also investigated. The results showed that in both methods, with increasing PbI2 concentration, thicker layers with higher adsorption can be prepared. | ||
| کلیدواژه‌ها [English] | ||
| Perovskite Absorber, Methylammonium Lead Iodide, Thin Film, Spin Coating, Dip Coating | ||
| مراجع | ||
|
[1] Wang, P., Guo, Y., Yuan, S., Yan, C., Lin, J., Liu, Z., Lu, Y., Bai, C., Lu, Q., Dai, S. and Cai, C., 2016. Advances in the structure and materials of perovskite solar cells. Research on Chemical Intermediates, 42, 625-639, (2016). [2] Zhang, W.H. and Cai, B., Organolead halide perovskites: a family of promising semiconductor materials for solar cells. Chinese Science Bulletin, 59, 2092-2101, (2014). [3] Grätzel, M., The light and shade of perovskite solar cells. Nature materials, 13, 838-842, (2014). [4] Wu, J., Lan, Z., Lin, J., Huang, M., Huang, Y., Fan, L. and Luo, G., Electrolytes in dye-sensitized solar cells. Chemical reviews, 115, 2136-2173, (2015). [5] Park, N.G., Perovskite solar cells: an emerging photovoltaic technology. Materials Today, 18, 65-72, (2015). [6] Boix, P.P., Nonomura, K., Mathews, N. and Mhaisalkar, S.G., Current progress and future perspectives for organic/inorganic perovskite solar cells. Materials today, 17, 16-23, (2014). [7] Zhang, S., Lanty, G., Lauret, J.S., Deleporte, E., Audebert, P. and Galmiche, L., Synthesis and optical properties of novel organic–inorganic hybrid nanolayer structure semiconductors. Acta Materialia, 57, 3301-3309, (2009). [8] Tanaka, K., Takahashi, T., Ban, T., Kondo, T., Uchida, K. and Miura, N., Comparative study on the excitons in lead-halide-based perovskite-type crystals CH 3 NH 3 PbBr 3 CH 3 NH 3 PbI 3. Solid state communications, 127, 619-623, (2003). [9] Luo, S. and Daoud, W.A., Crystal Structure Formation of CH3NH3PbI3-xClx Perovskite. Materials, 9, 123, (2016). [10] Eperon, G.E., Burlakov, V.M., Docampo, P., Goriely, A. and Snaith, H.J., Morphological control for high performance, solution‐processed planar heterojunction perovskite solar cells. Advanced Functional Materials, 24, 151-157, (2014). [11] Bing, J., Huang, S., & Ho-Baillie, A. W. A review on halide perovskite film formation by sequential solution processing for solar cell applications. Energy Technology, 8, 1901114, (2020). [12] Salau, A.M., Fundamental absorption edge in PbI 2: KI alloys. Solar Energy Materials, 2, 327-332, (1980). [13] Era, M., Hattori, T., Taira, T. and Tsutsui, T., Self-organized growth of PbI-based layered perovskite quantum well by dual-source vapor deposition. Chemistry of materials, 9, 8-10, (1997). [14] Kaya, Ismail C., Kassio PS Zanoni, Francisco Palazon, Michele Sessolo, Hasan Akyildiz, Savas Sonmezoglu, and Henk J. Bolink. "Crystal Reorientation and Amorphization Induced by Stressing Efficient and Stable P–I–N Vacuum‐Processed MAPbI3 Perovskite Solar Cells." Advanced Energy and Sustainability Research: 2000065, (2021). [15] Mitzi, D.B., Prikas, M.T. and Chondroudis, K., Thin Film Deposition of Organic− Inorganic Hybrid Materials Using a Single Source Thermal Ablation Technique. Chemistry of materials, 11, 542-544, (1999). [16] Burschka, J., Pellet, N., Moon, S.J., Humphry-Baker, R., Gao, P., Nazeeruddin, M.K. and Grätzel, M., Sequential deposition as a route to high-performance perovskitesensitized solar cells. Nature, 499, 316-319, (2013). [17] X. Zheng, Y. Hou, C. Bao, J. Yin, F. Yuan, Z. Huang, K. Song, J. Liu, J. Troughton, N. Gasparini, C. Zhou, Y. Lin, D.-J. Xue, B. Chen, A. K. Johnston, N. Wei, M. N. Hedhili, M. Wei, A. Y. Alsalloum, P. Maity, B. Turedi, C. Yang, D. Baran, T. D. Anthopoulos, Y. Han, Z.-H. Lu, O. F. Mohammed, F. Gao, E. H. Sargent, O. M. Bakr, Nat. Energy, 5, 131 (2020). [18] Jung, Eui Hyuk, Nam Joong Jeon, Eun Young Park, Chan Su Moon, Tae Joo Shin, Tae-Youl Yang, Jun Hong Noh, and Jangwon Seo. "Efficient, stable and scalable perovskite solar cells using poly (3-hexylthiophene)." Nature 567, 511-515, (2019). [19] Kong, W., Ye, Z., Qi, Z., Zhang, B., Wang, M., Rahimi-Iman, A. and Wu, H., Characterization of an abnormal photoluminescence behavior upon crystal-phase transition of perovskite CH 3 NH 3 PbI 3. Physical Chemistry Chemical Physics, 17, 16405-16411, (2015). [20] Baikie, T., Fang, Y., Kadro, J.M., Schreyer, M., Wei, F., Mhaisalkar, S.G., Graetzel, M. and White, T.J., Synthesis and crystal chemistry of the hybrid perovskite (CH 3 NH 3) PbI 3 for solid-state sensitised solar cell applications. Journal of Materials Chemistry A, 1, 5628-5641, (2013). [21] Takeo Oku, Kosyachenko, Leonid A., ed. Solar Cells: New approaches and reviews. BoD–Books on Demand, chapter 3, 2015. [22] Malliga, P., Pandiarajan, J., Prithivikumaran, N. and Neyvasagam, K., Influence of film thickness on structural and optical properties of sol–gel spin coated TiO2 thin film. J Appl Phys, 6, 22-28, (2014). [23] Liang, K., Mitzi, D. B., & Prikas, M. T. Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique. Chemistry of Materials, 10, 403–411, (1998). [24] Yuji Ando, Yuya Ohishi, Kohei Suzuki, Atsushi Suzuki, and Takeo Oku, Rietveld refinement of the crystal structure of perovskite solar cells using CH3NH3PbI3 and other compounds,AIP Conference Proceedings 1929, 020003, (2018). [25] Fu, Kunwu, Swee Sien Lim, Yanan Fang, Pablo P. Boix, Nripan Mathews, Tze Chien Sum, Lydia H. Wong, and Subodh Mhaisalkar. "Modulating CH 3 NH 3 PbI 3 perovskite crystallization behavior through precursor concentration." Nano: Brief Reports and Reviews, 9, 1440003, (2014). [26] Elangovan, E. and Ramamurthi, K., A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films. Applied Surface Science, 249, 183-196, (2005). [27] Jayan, K. Deepthi, and Varkey Sebastian. "A review on computational modelling of individual device components and interfaces of perovskite solar cells using DFT." In AIP Conference Proceedings, 2162, 020036, (2019). | ||
|
آمار تعداد مشاهده مقاله: 752 تعداد دریافت فایل اصل مقاله: 543 |
||